Foam Cleaner Safety Data Sheet

Safety Data Sheet 91/155/EEC (gb) FOMO® PU-Cleaner Var. A RATHOR AG Revised: 09.12.2003 01. Identification of the substance / preparation and of the company Product: FOMO® PU-Cleaner Var. A Use: For removal of fresh PU foam Company: RATHOR AG   Rütistraße   CH9050 Appenzell / SCHWEIZ Phone: 0041-71-7883636 Fax: 0041-71-7883600 eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it Homepage: www.rathor.ch Emergency phone: 0041-71-7883636 02. Composition / Information on ingredients Substance EINECS/ELINCS CAS Range [%] Symbol / R-phr. 1,1,1,2-Tetrafluoro ethane 212-377-0 811-97-2 1-<25 Acetone 200-662-2 67-64-1 50-<100 FΞ 11-36-66-67 Butane 203-448-7 106-97-8 1-<20 F+ 12 Carbon dioxide 204-696-9 124-38-9 1-<20 Dimethyl ether 204-065-8 115-10-6 1-<20 F+ 12 iso-Butane 200-857-2 75-28-5 1-<20 F+ 12 Propane 200-827-9 74-98-6 1-<20 F+ 12 03. Hazards identification R 12: Extremely flammable. R 36: Irritating to eyes. R 66: Repeated exposure may cause skin dryness or cracking. R 67: Vapours may cause drowsiness and dizziness. 04. First aid measures General information Change soaked clothing. Inhalation Ensure supply of fresh air. In the event of symptoms refer for medical treatment. Skin contact In case of contact with skin wash off with warm water . Consult a doctor if   skin irritation persists. Eye contact In case of contact with eyes rinse thoroughly with plenty of water and seek   medical advice. Ingestion Not applicable. Advice to doctor Treat symptomatically. 05. Fire-fighting measures Suitable extinguishing Carbon dioxide. Dry powder. Foam. Water spray jet. media Extinguishing media that Full water jet. must not be used Special exposure hazards Risk of formation of toxic pyrolysis products. arising from the substance or preparation itself or combustion products Special protective Use self-contained breathing apparatus. Do not inhale explosion and/or Chemiebüro Tel.+49-(0)941-566-398(-792), Fax.+49-(0)941-566-994 Page 1 of 5 www.chemiebuero.de/ eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it rat00060 gb en Safety Data Sheet 91/155/EEC (gb) FOMO® PU-Cleaner Var. A RATHOR AG Revised: 09.12.2003 equipment for firefighters combustion gases. Additional information Cool containers at risk with water spray jet. Fire residues and   contaminated firefighting water must be disposed of in accordance with   the local regulations. 06. Accidental release measures Personal precautions Ensure adequate ventillation . Keep away sources of ignition. Environmental precautions Not applicable. Methods for cleaning Take up mechanically. Dispose of absorbed material in accordance with up/taking up the regulations. 07. Handling and storage Advice on safe handling Use only in well-ventilated areas. Avoid spilling or spraying in enclosed   areas. Advice on protection Keep away from sources of ignition - refrain from smoking. against fire and explosion Requirements for storage Provide solvent-resistant and impermeable floor. rooms and vessels Advice on storage Do not store together with oxidizing agents. compatibility Further information on Protect from heat/overheating. Keep in a cool place, heat causes increase storage conditions in pressure and risk of bursting. 08. Exposure controls / personal protection Additional advice on system Ensure adequate ventilation on workstation. design Ingredients with occupational exposure limits to be monitored: Substance Value: 1,1,1,2-Tetrafluoro ethane LTEL: 1000ppm LTEL: 4240mg/m³ Acetone LTEL: 500ppm LTEL: 1210mg/m³ STEL: 1500ppm STEL: 3620mg/m³ (New IOELV, 88,96) Butane LTEL: 600ppm LTEL: 1450mg/m³ STEL: 750ppm STEL: 1810mg/m³ (60) Carbon dioxide LTEL: 5000ppm LTEL: 9150mg/m³ STEL: 15000ppm STEL: 27400mg/m³ (ILV) Dimethyl ether LTEL: 400ppm LTEL: 766mg/m³ STEL: 500ppm STEL: 958mg/m³ (IOELV) iso-Butane LTEL: 600ppm LTEL: 1450mg/m³ STEL: 750ppm STEL: 1810mg/m³ (60) Propane (Asphyxiant)   LTEL: Long-term exposure limit, STEL: Short-term exposure limit Respiratory protection Breathing apparatus in the event of high concentrations. Short term: filter   apparatus, Filter A. Hand protection Suitable protective gloves: Butyl rubber, >120 min (EN 374) Eye protection Safety glasses. Skin protection Not applicable. General protective measures Do not inhale aerosols. Avoid contact with eyes and skin. Hygiene measures At work do not eat, drink, smoke or take drugs. Use barrier skin cream. Chemiebüro Tel.+49-(0)941-566-398(-792), Fax.+49-(0)941-566-994 Page 2 of 5 www.chemiebuero.de/ eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it rat00060 gb en Safety Data Sheet 91/155/EEC (gb) FOMO® PU-Cleaner Var. A RATHOR AG Revised: 09.12.2003 Wash hands before breaks and after work. Delimitation and monitoring Not determinated. of the environmental exposition 09. Physical and chemical properties Form: Aerosol. Density [g/ml]: 0,83 Colour:   Bulk density [kg/m³]: Odour: Characteristic. Solubility in water: Miscible. pH-value: Not applicable. Partition coefficient: n- Not determinated.     octanol / water: Boiling point [°C]: Not applicable. Viscosity: Not applicable. Flash point [°C]: Not applicable. Relative vapour density Not applicable.     determined in air: Flammability: Not determinated. Evaporation speed: Not applicable. Lower explosion limit: Not determinated. Melting point [°C]: Not applicable. Upper explosion limit: Not determinated. Autoignition temperature: Not applicable. Combustible properties: No. Decomposition Not applicable. temperature: Vapour pressure [kPa]: Not determinated. 10. Stability and reactivity Hazardous reactions Because of the high vapour pressure, containers are liable to burst   iftemperature rises. Evolution of flammable mixtures possible in air when   heated above flash point and/or during spraying or misting. Hazardous decomposition No hazardous decomposition products known. products 11. Toxicological information Acute oral toxicity LD50 : OECD 401 LD50 : Acute dermal toxicity LD50 : OECD 402 Acute inhalational toxicity LC50 : OECD 403 Irritant effect on eye OECD Not determinated. 405 Irritant effect on skin OECD Not determinated. 404 Sensitization / Validation Not determinated. OECD 406 Subacute toxicity Not determinated. Chronic toxicity Not determinated. Mutagenicity / validation Not determinated. Reproduction toxicity / Not determinated. Validation Carcinogenicity / Validation Not determinated. Experiences made in None. practice Chemiebüro Tel.+49-(0)941-566-398(-792), Fax.+49-(0)941-566-994   Page 3 of 5 www.chemiebuero.de/ eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it   rat00060 gb en Safety Data Sheet 91/155/EEC (gb) FOMO® PU-Cleaner Var. A RATHOR AG Revised: 09.12.2003 General remarks No toxicological data are available. The product was classified on the basis of the calculation procedure of the preparation directive. 12. Ecological information Fish toxicity Not determinated. Behaviour in environment Not determinated. compartments Behaviour in sewage plant Not determinated. Bacteria toxicity Not determinated. Biological degradability Not determinated. Chemical oxygen demand (COD) Biochemical oxygen demand (BOD5) AOX-advice No dangerous components. Contains compounds of Not applicable. 76/464/EC General information Ecological data are not available. 13. Disposal considerations Disposal / Product Dispose of as hazardous waste. Waste no. (recommended) 160504* Disposal / Contaminated Uncontaminated packaging may be taken for recycling. Packaging that packaging cannot be cleaned should be disposed of as for product. 14. Transport information Classification according to ADR: ADR-Class: 2 Declaration: UN 1950 Aerosols 2.1 Labelling: UN 1950 Aerosole Factor, ADR 1.1.3.6: 3 Hazard-no: Label: 2.1 LQ, ADR 3.4.6: LQ2 Vapour pressure [kPa]: Classification according to IMDG: IMDG-Code-Class: 2.1 Declaration: Aerosols 2.1 UN 1950 - Labelling: Aerosols UN 1950 EmS: F-D, S-U Label: 2.1 LQ, [l/kg]: 1 Classification according to IATA: IATA-DGR-Class: 2.1 Declaration: Aerosols, flammable, Class: 2.1 UN 1950 Labelling: Aerosols, flammable UN 1950 Label: Flammable Gas Chemiebüro Tel.+49-(0)941-566-398(-792), Fax.+49-(0)941-566-994 Page 4 of 5 www.chemiebuero.de/ eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it rat00060 gb en Safety Data Sheet 91/155/EEC (gb) FOMO® PU-Cleaner Var. A RATHOR AG Revised: 09.12.2003 15. Regulatory information Labelling The product is classified and labelled in accordance with EC directives Hazard symbols Extremely flammable Irritant R 12: Extremely flammable. R 36: Irritating to eyes. R 66: Repeated exposure may cause skin dryness or cracking. R 67: Vapours may cause drowsiness and dizziness. S 23.4: Do not breathe spray. S 51: Use only in well-ventilated areas. S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 56: Dispose of this material and its container to hazardous or special waste collection point. Special labelling for certain preparations Container is under pressure. Protect from sun and temperatures above 50 °C. Do not open with force or incinerate even after use. Do not spray against an open flame or glowing hot objects. Keep away from sources of ignition - No smoking. Keep out of reach of children. National regulations Not applicable. 16. Other informations R phrases(Information on ingredients - 02) R 11: Highly flammable. R 12: Extremely flammable. R 36: Irritating to eyes. R 66: Repeated exposure may cause skin dryness or cracking. R 67: Vapours may cause drowsiness and dizziness. Regulatory information * 91/155 (2001/58) * 67/548 (2001/59) * 1999/45 (2001/60) * 91/689 (2001/118) * 89/542 * ADR (2003) * IMDG-Code (31.Amdt.) * IATA-DGR (2003) Modified position: 14, 16 Chemiebüro Tel.+49-(0)941-566-398(-792), Fax.+49-(0)941-566-994 Page 5 of 5 www.chemiebuero.de/ eMail: This e-mail address is being protected from spam bots, you need JavaScript enabled to view it rat00060 gb en